Processes
The full gamut of photographic printing processes may be little-known to
contemporary photographers, who have been educated largely within the mainstream
of the silver-gelatine tradition. My intention here is to help restore some
of the 'lost' options by providing you with a handy reference list of the
better-known alternative processes and an outline of their characteristics
and working methods, without any detailed formulae or procedures. This should
enable you to decide if 'there might be anything in it for you'. If so,
then the texts listed in my bibliography should provide you with an entry
into the practice, but the best practical introduction is to enrol on one
of the advertised workshops that take place from time to time - in the UK
under the aegis of the Royal Photographic Society, the Photographers'
Place or one of the regional photographic galleries.
This account is a sequel to my earlier Defence of Alternative Process
in Contemporary Photography No.1 and it may be read as a supplement
to Hope Kingsley's excellent article in The Photographic Journal
for September 1988, which addresses the subject from the historical viewpoint,
providing a background to that successful RPS exhibition An A to Z of
Photographic Processes.
Any photographic printing material that does not originate from a box labelled
with one of the well-known commercial brand names may be described as 'historical',
'alternative', 'non-silver', 'unconventional', 'obsolete' or even 'archaic'.
Nearly all such materials must be hand-made (though palladium paper is now
commercially available once again in the USA) so the practices tend to be
labour-intensive and their use does not increase any shareholders' dividends!
Most of the methods fall into three categories from the photochemical point
of view, depending on the light-sensitive metal compound involved: whether
it's a salt of silver, iron or chromium. The list at the end of this article
is by no means exhaustive; there are some strange
processes on record. I should be glad to hear of any processes I have
omitted that are still known to be in current use. The historical attributions
are necessarily oversimplified because many of the processes are not just
due to the endeavours of one person.
Limitations
Compared with modern silver-gelatine printing, the conspicuous disadvantage
of most alternative processes is their low 'speed' in the photographic sense,
because the sensitivity of the coatings to light is about a million times
less than that of bromide enlarging papers. (Obviously this generalization
does not apply to Carbro and Bromoil which actually start with a gelatine-silver
bromide print as substrate). This disadvantage was largely responsible for
the early commercial demise of alternative processes such as Platinotype
at the same time as the market for miniature cameras and bromide enlarging
papers was growing. Projection printing being generally impractical with
the technology normally available, we must resort to contact printing as
the only way to achieve sufficient light intensity: the technologist will
opt for a mercury lamp as ultra-violet light source, but the mystics will
prefer to 'sun-print' in the time-honoured fashion -especially if they enjoy
a good climate! One compensation for the insensitivity of these processes
is that they do not demand an enlarger or darkroom. Another, less obvious
benefit is that these imaging systems are in principle capable of extremely
high resolution; modern technology has rediscovered dichromated gelatine
as an ideal material for recording holographic information, for instance.
It should also be acknowledged that dichromated colloids have always found
an essential application within the printing industry as the basis for several
methods of photomechanical reproduction.
Strategies
The enforced necessity for contact-printing leaves the 35 mm/roll-film practitioner
with a choice of three possible photographic strategies:
- to make very small prints,
- to move up to large format equipment,
- to make internegatives by enlargement.
What are the relative merits? (1) produces exquisite gems -that can only
be viewed through a magnifier! (2) can yield breathtaking results, but entails
all the expense and difficulty of large format working and an irreversible
act of commitment, for the following reason: many of the alternatives require
a negative to be developed to such high contrast that it will be unprintable
thereafter in conventional silver-gelatine. Strategy (3) offers a useful
compromise, especially for those wishing to explore the processes for the
first time. It is conveniently accomplished by using one of the direct duplicating
films (e.g. Kodak SO-339) in 5"x4" or 10"x8" size, to
make a high contrast (if need be) internegative from the original. An enlarger
is used in much the same manner as for conventional printing, and with all
the same potential for image manipulation at this stage, if so desired.
A less expensive alternative favoured by some is to make interpositives
and internegatives on paper.
Modus Operandi
The following steps outline a procedure typical of an iron-based process
(the others may differ in some respects).
- If the photographer is given to the large-format ethos, the picture
will be composed on the ground glass, in the knowledge that this is the
real image that will fall on the film and not, as with viewfinder and reflex
cameras, some optical derivative of it. Any misjudgement is entirely attributable
to the operator, not the equipment! To use the acronym beloved of word-processor
buffs: "WYSIWYG" - "What You See Is What You Get".
- Negative-making can employ the best modern technology, or not, according
to taste (pace the calotypists, pinholists and other 'low-tech' photographers
-I have no argument with you!) In order to match the negative density range
to the intended printing process, it is likely that a procedure of calibrated
metering, exposure and development - e.g. the Zone System- will be used.
(The original motivation for the Zone System was to enable the photographer
to print every negative using only a single grade of paper. These days,
having many exposures on a roll and paper grades 1 to 6 or Multigrade technology,
some of us have become lazy negative makers.)
- For printing the image, a fine-art paper is selected from the great
range intended for watercolourists, etchers and printmakers, with regard
to the suitability of its tint, surface texture, weight, sizing, etc. The
papermakers could do us a great favour here by re-introducing products once
especially suited for alternative photographic processes. For photographers
inured to the bland gloss or mechanical stipple of commercial silver-gelatine,
it may be a pleasure to rediscover that paper can be a beautiful material!
- The sensitizer chemicals are mixed - demanding no special skills beyond
those of any darkroom practitioner. There are usually decisions to be made
at this point regarding the intended colour and contrast of the image.
- A batch of paper is now coated by hand with the sensitizer solution;
various techniques may be used - according to the skill (and flamboyance!)
of the individual.
- After drying, the sensitized paper is contact-printed from the negative
using the preferred light source. Some of the processes provide a 'printout'
image, which may be inspected as it builds up, using the old-fashioned style
of printing frame with a hinged back to retain registration. The need for
test strips is thus avoided: "WYSIWYG" again! Printout also has
the built-in advantage of being self-masking to some extent, so the process
will tolerate a long density range in the negative and be non-critical in
exposure time.
- Wet processing of the print follows, under ordinary tungsten lighting.
Some processes (e.g. Bromoil) demand extensive 'handwork' at this stage;
in others, like Gum Bichromate, it is an available option, whereas the 'straightest'
processes (e.g. Platinotype) offer little or no scope for intervention in
the processing. Chacun á son gout.
- Washing, drying, retouching and mounting are all simple, especially
in the iron-based processes because the paper surface does not carry an
organic binder layer and is very sympathetic to treatment.
- In some practices, e.g. Gum-Bichromate, the operator may now return
to step 4 in order to make a multiple print.
Conclusion
I hope that this brief description of alternative printmaking will enable
interested readers to decide whether they might love it or leave it. I have
tried to convey something of the 'holistic' nature of the activity, in which
being true to one's materials is a satisfaction in its own right. Perhaps
Ansel Adams - not, admittedly, an enthusiast for alternative processes -
would have forgiven me for invoking his nice analogy between the arts of
music and photography, in which the musical score represents the negative
and the concert performance, the final print. My belief is that however
unique and unalterable the score, our pleasure in the work must ultimately
depend upon the richness and variety of the performance.
First published in Contemporary Photography No.3 (1991).
ALTERNATIVE PHOTOGRAPHIC PRINTING PROCESSES:
SILVER BASED
| Process |
Sensitizer/binder |
Image |
Inventor |
Year |
| Salt print |
Silver chloride/none |
Silver |
Talbot |
1834 |
| Albumen |
Silver chloride/albumen |
Silver |
Evrard |
1850 |
| Collodion |
Silver chloride/collodion |
Silver |
Simpson |
1865 |
| Print-out |
Silver chloride/gelatin |
Silver |
Mawdsley |
1874 |
| Ozobrom |
Silver bromide/gelatine
contact diffusion |
Pigments |
Manly |
1905 |
| Bromoil |
Silver bromide/gelatine
dichromate bleach & harden
|
Litho Ink |
Piper & Wall |
1907 |
| Carbro |
Silver bromide/gelatine
contact diffusion |
Pigment |
Farmer |
1919 |
ALTERNATIVE PHOTOGRAPHIC PRINTING PROCESSES:
IRON-BASED
| Process |
Sensitizer (Developer) |
Image |
Inventor |
Year |
| Argentotype |
Ferricitrate
(Dev: Silver nitrate) |
Silver |
Herschel |
1842 |
Vandyke
Brownprint
Sepiaprint |
Ferricitrate+Silver nitrate
(Dev: water) |
Silver |
Arndt &
Troost |
1889 |
| Kallitype |
Ferric oxalate + Silver nitrate
(Dev: Borax or Rochelle salt) |
Silver |
Hunt
Nicol |
1844
1889 |
| Argyrotype |
Ferricitrate+Silver sulphamate
(Dev: water)
|
Silver |
Ware |
1991 |
Cyanotype
Blueprint
Ferroprussiate |
Ferricitrate+Ferricyanide
(Dev: water) |
Prussian
Blue |
Herschel |
1842 |
| New Cyanotype |
Ferrioxalate+ferricyanide
(Dev: dil. nitric acid) |
Prussian
Blue |
Ware |
1992 |
| Pellet Print |
Ferricitrate/tartrate
(Dev: Ferrocyanide+gum) |
Prussian
Blue |
Herschel
Pellet |
1842
1878 |
| Chrysotype |
Ferricitrate
(Dev: chloroaurate(III)) |
Gold |
Herschel |
1842 |
| New Chrysotype |
Ferrioxalate+gold(I) complex
(Dev: carboxylic acids) |
Gold |
Ware |
1987 |
| Platinotype |
Ferric oxalate+chloroplatinite
(Dev: oxalate) |
Platinum |
Willis |
1873 |
| Sepia Platinum |
Ferric oxalate+chloroplatinite
+Mercury(II) salts
(Dev: oxalate) |
Mercury+
Platinum |
Willis |
1890 |
| POP Platinum |
Sodium ferrioxalate + sodium chloroplatinite |
Platinum |
Pizzighelli |
1887 |
| Satista |
Ferric oxalate+silver chloride +chloroplatinite |
Silver+ Platinum |
Willis |
1913 |
| Palladiotype |
Ferric oxalate+chloropalladite
(Dev: oxalate) |
Palladium |
Willis |
1916 |
| Amphitype |
Ferricitrate/ferritartrate +Mercury(II) salts |
Mercury |
Herschel |
1842 |
| Obernetter's Ferrocupric |
Ferric chloride+cupric chloride
(Dev: thiocyanate)
(Tone: ferricyanide) |
Cupric
Ferrocyanide |
Obernetter |
1864 |
| Phipson's |
Ferrioxalate
(Dev: permanganate) |
Manganese
Dioxide |
Phipson |
1861 |
Ferrogallate
Colas
Blackline |
Ferritartrate
(Dev: Gallic acid) |
Ferric
Gallate |
Colas |
1860 |
Heliographic
Nakahara's |
Ferritartrate
(Dev: Tannic acid) |
Ferric
Tannate |
Nakahara |
1894 |
ALTERNATIVE PHOTOGRAPHIC PRINTING PROCESSES:
CHROMIUM BASED
| Process |
Sensitizer/Colloid |
Image |
Inventor |
Year |
| Gum Bichromate |
Dichromate/gum arabic |
Pigment |
Poitevin |
1855 |
| Carbon (direct) |
Dichromate/gelatine |
Pigment |
Poitevin |
1855 |
| Carbon Transfer |
Dichromate/gelatine |
Pigment |
Fargier |
1860 |
| Fresson |
Dichromate/colloid |
Pigment |
Fresson |
1899 |
| Oil print |
Dichromate/gelatine |
Litho Ink |
Rawlins |
1904 |
| Ozotype |
Dichromate/gelatine
|
Pigment |
Manly |
1899 |
| Gum-Ozotype |
Dichromate/gum arabic |
Pigment |
Manly |
1899 |